Please use this identifier to cite or link to this item: http://hdl.handle.net/20.500.12666/618
Title: Raman spectroscopy and planetary exploration: Testing the ExoMars/RLS system at the Tabernas Desert (Spain)
Authors: Veneranda, M.
López Reyes, G.
Manrique Martínez, J. A.
Sánz Arranz, A.
Medina, J.
Pérez, C.
Quintana, C.
Moral, A.
Rodríguez, J. A.
Zafra, J.
Nieto Calzada, L. M.
Rull, F.
Keywords: Ramn;Mars;ExoMars;RLS;Terrestrial Analogue;Biomarkers
Issue Date: 12-Jun-2021
Publisher: Elsevier BV
DOI: 10.1016/j.microc.2021.106149
Published version: https://www.sciencedirect.com/science/article/abs/pii/S0026265X21002332
Citation: Microchemical Journal 165: 106149(2021)
Abstract: ExoFit trials are field campaigns financed by ESA to test the Rosalind Franklin rover and to enhance collaboration practices between ExoMars working groups. During the first trial, a replicate of the ExoMars rover was remotely operated from Oxfordshire (United Kingdom) to perform a complex sequence of scientific operation at the Tabernas Desert (Spain). By following the ExoMars Reference Surface Mission (RSM), the rover investigated the Badlands subsoil and collected drill cores, whose analytical study was entrusted to the RLS (Raman Laser Spectrometer) team. The preliminary characterization of core samples was performed in situ through the RLS Engineering and Qualification Model (EQM-2) and the Raman Demonstrator (RAD1), being this a new, portable emulator of the RLS. In situ results where then complemented by laboratory analysis using the RLS ExoMars simulator and the commercial version of the Curiosity/CheMin XRD system. Raman data, obtained by closely simulating the operational constraints of the mission, successfully disclosed the mineralogical composition of the samples, reaching the detection of minor/trace phases that were not detected by XRD. More importantly, Raman analysis detected many vibrational peaks potentially emitted by organic functional groups, thus suggesting the presence of microorganisms in the arid sub-surface of the Tabernas Desert. In light of the forthcoming ExoMars mission, the results here presented proves that RLS could play a critical role in the characterization of Martian sub-surface environments and in the analytical detection of potential traces of live.
Description: Highlights The ExoMars mission to Mars was simulated at the Tabernas Desert (ExoFiT trials) Raman spectrometers were used the laboratory to analyse the drilled cores. The main mineralogical phases were successfully detected in-situ by the RLS EQM-2. The RLS ExoMars simulator detected additional minerals and organic compounds. The suitability of Raman spectroscopy for space exploration missions was disclosed.
URI: http://hdl.handle.net/20.500.12666/618
E-ISSN: 1095-9149
ISSN: 0026-265X
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