The Chemical Structure of Young High-mass Star-forming Clumps. II. Parsec-scale CO Depletion and Deuterium Fraction of HCO+

Abstract

The physical and chemical properties of cold and dense molecular clouds are key to understanding how stars form. Using the IRAM 30 m and NRO 45 m telescopes, we carried out a Multiwavelength line-Imaging survey of the 70 μm-dArk and bright clOuds (MIAO). At a linear resolution of 0.1–0.5 pc, this work presents a detailed study of parsec-scale CO depletion and HCO+ deuterium (D-) fractionation toward four sources (G11.38+0.81, G15.22–0.43, G14.49–0.13, and G34.74–0.12) included in our full sample. In each source with T < 20 K and nH ~ 104–105 cm−3, we compared pairs of neighboring 70 μm bright and dark clumps and found that (1) the H2 column density and dust temperature of each source show strong spatial anticorrelation; (2) the spatial distribution of CO isotopologue lines and dense gas tracers, such as 1–0 lines of H13CO+ and DCO+, are anticorrelated; (3) the abundance ratio between C18O and DCO+ shows a strong correlation with the source temperature; (4) both the C18O depletion factor and D-fraction of HCO+ show a robust decrease from younger clumps to more evolved clumps by a factor of more than 3; and (5) preliminary chemical modeling indicates that chemical ages of our sources are ~8 × 104 yr, which is comparable to their free-fall timescales and smaller than their contraction timescales, indicating that our sources are likely dynamically and chemically young.