Metrological analysis on measuring techniques used to determine solubility of solids in supercritical carbon dioxide

Perez Sanz, Fernando; Mohíno Herranz, Inmaculada; Bazito, Reinaldo C.

Publicación:
Metrological analysis on measuring techniques used to determine solubility of solids in supercritical carbon dioxide

dc.contributor.author	Perez Sanz, Fernando
dc.contributor.author	Mohíno Herranz, Inmaculada
dc.contributor.author	Bazito, Reinaldo C.
dc.date.accessioned	2026-02-20T12:07:03Z
dc.date.available	2026-02-20T12:07:03Z
dc.date.issued	2024-09-02
dc.description.abstract	Supercritical carbon dioxide is commonly used as a green solvent in extraction processes. Precise data on the phase equilibrium of the mixture are vital to optimize process efficiency. The solutes extracted with scCO2 can exist in either a solid or liquid phase. The techniques developed to measure equilibrium, though similar, differ depending on the solute’s state. This work selects the most commonly used measuring techniques to determine the solubility of solids in scCO2 and analyzes the main sources of uncertainty. Six techniques are presented, studied, and compared: semi-flow, static analytic, static synthetic, chromatographic, capacitance cell, and nuclear magnetic resonance. The static synthetic method exhibits the lowest uncertainty, Ur(s) = 0.40 %, followed closely by the semi-flow method, Ur(s) = 0.50 %. Nuclear magnetic resonance is reported to have the highest uncertainty according to the literature, Ur(s) = 6 %. Other aspects, such as pricing or experimentation time, are also considered in the comparison, but no real analysis was performed since these characteristics are more volatile.
dc.description.peerreviewed	Peerreview
dc.identifier.citation	Measurement 240: 115502
dc.identifier.doi	10.1016/j.measurement.2024.115502
dc.identifier.e-issn	1873-412X
dc.identifier.issn	0263-2241
dc.identifier.other	https://www.sciencedirect.com/science/article/abs/pii/S0263224124013873
dc.identifier.uri	https://hdl.handle.net/20.500.12666/1742
dc.language.iso	eng
dc.publisher	Elsevier
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dc.rights.accessRights	info:eu-repo/semantics/restrictedAccess
dc.rights.license	© 2024 Elsevier Ltd.
dc.subject	Metrological
dc.subject	Carbon dioxide
dc.title	Metrological analysis on measuring techniques used to determine solubility of solids in supercritical carbon dioxide
dc.type	info:eu-repo/semantics/article
dc.type.coar	http://purl.org/coar/resource_type/c_2df8fbb1
dc.type.hasVersion	info:eu-repo/semantics/publishedVersion
dspace.entity.type	Publication
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