Persona: Parrondo, María Concepción
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Publicación Acceso Abierto Chemical depletion of Arctic ozone in winter 1999/2000(American Geophysical Union, 2002-09-20) Rex, Markus; Salawitch, R. J.; Harris, Neil R. P.; Gathen, Peter von der; Braathen, Geir O.; Schulz, Astrid; Deckelmann, H.; Chipperfield, M.; Sinnhuber, B. M.; Reimer, E.; Alfier, R.; Bevilacqua, R.; Hoppel, K.; Fromm, M.; Lumpe, J.; Küllmann, H.; Kleinböhl, A.; Bremer, H.; Von König, M.; Künzi, K.; Toohey, D.; Vömel, H.; Richard, E.; Aikin, K.; Jost, H.; Greenblatt, J. B.; Loewenstein, M.; Podolske, J. R.; Webster, Christopher R.; Flesch, Gregory J.; Scott, D. C.; Herman, R. L.; Elkins, J. W.; Ray, E. A.; Moore, F. L.; Hurst, D. F.; Romashkin, P.; Toon, G. C.; Sen, B.; Margitan, J. J.; Wennberg, P.; Neuber, R.; Allart, M.; Bojkov, B. R.; Claude, H.; Davies, Jonathan; Davies, W.; De Backer, H.; Dier, Horst; Dorokhov, Valery; Fast, H.; Kondo, Yutaka; Kyrö, Esko; Litynska, Z.; Mikkelsen, I. S.; Molyneux, M. J.; Moran, E.; Nagai, T.; H. Nakane; Parrondo, María Concepción; Ravegnani, Fabrizio; Skrivánková, Pavla; Viatte, P.; Yushkov, Vladimir; European Commission (EC); National Aeronautics and Space Administration (NASA)[1] During Arctic winters with a cold, stable stratospheric circulation, reactions on the surface of polar stratospheric clouds (PSCs) lead to elevated abundances of chlorine monoxide (ClO) that, in the presence of sunlight, destroy ozone. Here we show that PSCs were more widespread during the 1999/2000 Arctic winter than for any other Arctic winter in the past two decades. We have used three fundamentally different approaches to derive the degree of chemical ozone loss from ozonesonde, balloon, aircraft, and satellite instruments. We show that the ozone losses derived from these different instruments and approaches agree very well, resulting in a high level of confidence in the results. Chemical processes led to a 70% reduction of ozone for a region ∼1 km thick of the lower stratosphere, the largest degree of local loss ever reported for the Arctic. The Match analysis of ozonesonde data shows that the accumulated chemical loss of ozone inside the Arctic vortex totaled 117 ± 14 Dobson units (DU) by the end of winter. This loss, combined with dynamical redistribution of air parcels, resulted in a 88 ± 13 DU reduction in total column ozone compared to the amount that would have been present in the absence of any chemical loss. The chemical loss of ozone throughout the winter was nearly balanced by dynamical resupply of ozone to the vortex, resulting in a relatively constant value of total ozone of 340 ± 50 DU between early January and late March. This observation of nearly constant total ozone in the Arctic vortex is in contrast to the increase of total column ozone between January and March that is observed during most years.Publicación Acceso Abierto The Mars Environmental Dynamics Analyzer, MEDA. A Suite of Environmental Sensors for the Mars 2020 Mission(Springer Link, 2021-04-13) Rodríguez Manfredi, J. A.; De la Torre Juárez, M.; Alonso, A.; Apéstigue, Víctor; Arruego, Ignacio; Atienza, T.; Banfield, D.; Boland, J.; Carrera, M. A.; Castañer, L.; Ceballos Cáceres, J.; Chen Chen, H.; Cobos, A.; Conrad, Pamela G.; Cordoba, E.; Del Río Gaztelurrutia, T.; Vicente Retortillo, Álvaro; Domínguez Pumar, M.; Espejo, S.; Fairén, Alberto G.; Fernández Palma, A.; Ferrándiz, Ricardo; Ferri, F.; Fischer, E.; García Manchado, A.; García Villadangos, M.; Genzer, María; Giménez, Á.; Gómez Elvira, J.; Gómez, Felipe; Guzewich, Scott; Harri, Ari-Matti; Hernández, C. D.; Hieta, M.; Hueso, R.; Jaakonaho, I.; Jiménez Martín, Juan José; Jiménez, V.; Larman, A.; Leiter, R.; Lepinette Malvitte, A.; Lemmon, M. T.; López, G.; Madsen, Soren N.; Mäkinen, T.; Marín Jiménez, M.; Martín Soler, J.; Martínez, Germán M.; Molina, A.; Mora Sotomayor, L.; Moreno Álvarez, J. F.; Navarro López, Sara; Newman, C. E.; Ortega, Cristina; Parrondo, María Concepción; Peinado, V.; Peña, A.; Pérez Grande, I.; Pérez Hoyos, S.; Pla García, J.; Polkko, J.; Postigo, M.; Prieto-Ballesteros, Olga; Rafkin, Scot C. R.; Ramos, Miguel; Richardson, M. I.; Romeral, J.; Romero Guzmán, Catalina; Runyon, Kirby; Saiz López, A.; Sánchez Lavega, Agustín; Sard, I.; Schofield, J. T.; Sebastián, E.; Smith, Michael D.; Sullivan, Robert; Tamppari, L. K.; Thompson, A. D.; Toledo, D.; Torrero, F.; Torres, J.; Urquí, R.; Velasco, T.; Viúdez Moreiras, Daniel; Zurita, S.; Agencia Estatal de Investigación (AEI); European Research Council (ERC); Gobierno Vasco; Rodríguez Manfredi, J. A. [0000-0003-0461-9815]; Saiz López, A. [0000-0002-0060-1581]; Chen, H. [0000-0001-9662-0308]; Pérez Hoyos, S. [0000-0002-2587-4682]NASA’s Mars 2020 (M2020) rover mission includes a suite of sensors to monitor current environmental conditions near the surface of Mars and to constrain bulk aerosol properties from changes in atmospheric radiation at the surface. The Mars Environmental Dynamics Analyzer (MEDA) consists of a set of meteorological sensors including wind sensor, a barometer, a relative humidity sensor, a set of 5 thermocouples to measure atmospheric temperature at ∼1.5 m and ∼0.5 m above the surface, a set of thermopiles to characterize the thermal IR brightness temperatures of the surface and the lower atmosphere. MEDA adds a radiation and dust sensor to monitor the optical atmospheric properties that can be used to infer bulk aerosol physical properties such as particle size distribution, non-sphericity, and concentration. The MEDA package and its scientific purpose are described in this document as well as how it responded to the calibration tests and how it helps prepare for the human exploration of Mars. A comparison is also presented to previous environmental monitoring payloads landed on Mars on the Viking, Pathfinder, Phoenix, MSL, and InSight spacecraft.Publicación Acceso Abierto Validation of Aura Microwave Limb Sounder Ozone by ozonesonde and lidar measurements(AGU Publishing, 2007-12-15) Jiang, T. B.; Froidevaux, L.; Lambert, A.; Livesey, N. J.; Read, W. G.; Waters, J. W.; Bojkov, B.; Leblanc, T.; Mcdermid, I. S.; Godin-Beekmann, S.; Filipiak, M. J.; Harwood, R. S.; Fuller, R. A.; Daffer, W. H.; Drouin, B. J.; Cofield, R. E.; Cuddy, D. T.; Jarnot, R. F.; Knosp, B. W.; Perun, V. S.; Schwartz, M. J.; Snyder, W. V.; Stek, P. C.; Thurstans, R. P.; Wagner, P. A.; Allaart, M.; Andersen, S. B.; Bodeker, G.; Calpini, B.; Claude, H.; Coetzee, G.; Davies, J.; De Backer, H.; Dier, H.; Fujiwara, M.; Johnson, B.; Kelder, H.; Leme, N. P.; König Langlo, G.; Kyrö, Esko; Laneve, G.; Fook, L. S.; Merrill, J.; Morris, G.; Newchurch, M.; Oltmans, S.; Parrondo, María Concepción; Posny, F.; Schmidlin, F.; Skrivankova, P.; Stubi, R.; Tarasick, D.; Thompson, A.; Thouret, V.; Viatte, P.; Vömel, H.; Von der Gathen, P.We present validation studies of MLS version 2.2 upper tropospheric and stratospheric ozone profiles using ozonesonde and lidar data as well as climatological data. Ozone measurements from over 60 ozonesonde stations worldwide and three lidar stations are compared with coincident MLS data. The MLS ozone stratospheric data between 150 and 3 hPa agree well with ozonesonde measurements, within 8% for the global average. MLS values at 215 hPa are biased high compared to ozonesondes by ∼20% at middle to high latitude, although there is a lot of variability in this altitude region. Comparisons between MLS and ground-based lidar measurements from Mauna Loa, Hawaii, from the Table Mountain Facility, California, and from the Observatoire de Haute-Provence, France, give very good agreement, within ∼5%, for the stratospheric values. The comparisons between MLS and the Table Mountain Facility tropospheric ozone lidar show that MLS data are biased high by ∼30% at 215 hPa, consistent with that indicated by the ozonesonde data. We obtain better global average agreement between MLS and ozonesonde partial column values down to 215 hPa, although the average MLS values at low to middle latitudes are higher than the ozonesonde values by up to a few percent. MLS v2.2 ozone data agree better than the MLS v1.5 data with ozonesonde and lidar measurements. MLS tropical data show the wave one longitudinal pattern in the upper troposphere, with similarities to the average distribution from ozonesondes. High upper tropospheric ozone values are also observed by MLS in the tropical Pacific from June to November.Publicación Restringido Design of a planetary protection cover for EMC testing of a spacial magnetic sensor(Institute of Electrical and Electronics Engineers, 2019-10-17) Fernández Romero, S.; Parrondo, María Concepción; Díaz Michelena, Marina; Muñóz Rebate, I.; León Calero, Marina; Martín Iglesias, Santiago; Plaza Gallardo, Borja; Escot Bocanegra, D.; Poyatos Martinez, David; Jiménez Lorenzo, María; López Sanz, Daniel; Ministerio de Economía y Competitividad (MINECO); Agencia Estatal de Investigación (AEI)This paper explains the research process carried out for the development and manufacture of the planetary protection cover for carrying out the electromagnetic compatibility (EMC) tests of the an-isotropic magneto-resistance (AMR) sensor of the ExoMars 2020 mission. This mission has strict bioburden requirements. The electromagnetic properties of several materials have been analyzed in order to study their transmission coefficient and the innovation of this project is the use of fused deposition modeling (FDM) technology as manufacturing method. Additive manufacturing is presented as a promising technology in the field of radiofrequency since it can use a wide range of polymeric materials (thermoplastics) with low transmission coefficient. Observing the electromagnetic (EM) characterization results, it was decided to manufacture a protective cover using FDM technology, because it allows control over the grounding of the instrument and facilitates the integration, cleaning and protection against impacts during the manipulation, with great versatility and low cost. Finally, the cover has been verified during the acceptance EMC tests of the flight model AMR instrument.Publicación Restringido Unprecedented Arctic ozone loss in 2011(Springer Nature, 2011-10-02) Manney, Gloria; Santee, Michelle; Rex, Markus; Livesey, Nathaniel; Pitts, Michael; Veefkind, Pepijn; Nash, Eric; Wohltmann, Ingo; Lehmann, Ralph; Froidevaux, Lucien; Poole, Lamont; Schoeberl, Mark; Haffner, David; Davies, Jonathan; Dorokhov, Valery; Gernandt, Hartwig; Johnson, Bryan; Kivi, Rigel; Kyrö, Esko; Larsen, Niels; Levelt, Pieternel; Makshtas, Alexander; Mcelroy, Thomas; Nakajima, Hideaki; Parrondo, María Concepción; Tarasick, David; Von der Gathen, Peter; Walker, Kaley; Zinoviev, NikitaChemical ozone destruction occurs over both polar regions in local winter–spring. In the Antarctic, essentially complete removal of lower-stratospheric ozone currently results in an ozone hole every year, whereas in the Arctic, ozone loss is highly variable and has until now been much more limited. Here we demonstrate that chemical ozone destruction over the Arctic in early 2011 was—for the first time in the observational record—comparable to that in the Antarctic ozone hole. Unusually long-lasting cold conditions in the Arctic lower stratosphere led to persistent enhancement in ozone-destroying forms of chlorine and to unprecedented ozone loss, which exceeded 80 per cent over 18–20 kilometres altitude. Our results show that Arctic ozone holes are possible even with temperatures much milder than those in the Antarctic. We cannot at present predict when such severe Arctic ozone depletion may be matched or exceeded.Publicación Acceso Abierto Arctic winter 2005: Implications for stratospheric ozone loss and climate change(AGU Publishing, 2006-12-08) Rex, M.; Salawitch, R. J.; Deckelmann, H.; Von der Gathen, P.; Harris, N. R. P.; Chipperfield, M. P.; Naujokat, B.; Reimer, E.; Allaart, M.; Andersen, S. B.; Bevilacqua, R.; Braathen, G. O.; Claude, H.; Davies, J.; De Backer, H.; Dier, H.; Dorokhov, V.; Fast, H.; Gerding, M.; Godin Beekmann, S.; Hoppel, K.; Johnson, B.; Kyrö, Esko; Litynska, Z.; Moore, D.; Nakane, H.; Parrondo, María Concepción; Risley, A. D.; Skrivankova, P.; Stübi, R.; Viatte, P.; Yushkov, V.; Zerefos, C.[1] The Arctic polar vortex exhibited widespread regions of low temperatures during the winter of 2005, resulting in significant ozone depletion by chlorine and bromine species. We show that chemical loss of column ozone (ΔO3) and the volume of Arctic vortex air cold enough to support the existence of polar stratospheric clouds (VPSC) both exceed levels found for any other Arctic winter during the past 40 years. Cold conditions and ozone loss in the lowermost Arctic stratosphere (e.g., between potential temperatures of 360 to 400 K) were particularly unusual compared to previous years. Measurements indicate ΔO3 = 121 ± 20 DU and that ΔO3 versus VPSC lies along an extension of the compact, near linear relation observed for previous Arctic winters. The maximum value of VPSC during five to ten year intervals exhibits a steady, monotonic increase over the past four decades, indicating that the coldest Arctic winters have become significantly colder, and hence are more conducive to ozone depletion by anthropogenic halogens.Publicación Acceso Abierto The September 2002 Antarctic vortex major warming as observed by visible spectroscopy and ozone soundings(Taylor & Francis Ltd, 2005-08) Yela González, Margarita; Parrondo, María Concepción; Gil Moulet, Manuel; Rodríguez, S.; Araujo, J.; Ochoa, H.; Deferrari, Guillermo Alejandro; Diaz, Susana BeatrizThe record of O3 total column and NO2 obtained by visible spectroscopy at Ushuaia (55° S), Marambio (64° S) and Belgrano (78° S) and vertical ozone profiles from the latter station provide insight into the unprecedented major warming observed above Antarctica in the last week of September 2002. From 18 September to 25 September the temperature increased 54°C at the isentropic level of 700 K. The temperature anomaly was observed down to the level of 300 K in which a well-defined tropopause was established. From comparison of the ozone profiles before and during the event, it can be seen that a fast increase in O3 took place basically above 500 K, but the layer where the ozone hole occurs was barely affected. Low potential vorticity values above Belgrano occurred only at levels above 500 K, confirming that the vortex split was confined to heights above the layer of the Antarctic spring depletion. The signature of poleward-transported air is clearly visible from the NO2 column departure from the envelope of the previous years in all three stations. NO2 columns larger than typical for ozone hole conditions by 400% were observed at Belgrano. Diurnal variations provide evidence of non-denitrified extra-vortex air.Publicación Restringido OClO, NO2 and O3 total column observations over Iceland during the winter 1993/94(AGU Publishing, 1996-11-15) Gil, M.; Puentedura, O.; Yela González, Margarita; Parrondo, María Concepción; Jadhav, D. B.; Thorkelsson, B.Ground-based observation of OClO, NO2, and O3 columns by differential UV-Visible spectroscopy at twilight during the fall winter of 1993/94 at the sub-Arctic station of Reykjavik (64°N, 23°W) are presented. Results show no direct evidence of ozone depletion during the period but significant amounts of OClO were observed in December and January when NO2 abundances were at the annual minimum. NO2 columns are found to be controlled by the hours of light available but highly modulated by the lower stratosphere temperature. OClO was observed outside the vortex as well, but only at times when NO2 was low.Publicación Acceso Abierto A trajectory-based estimate of the tropospheric ozone column using the residual method(AGU Publishing, 2007-12-19) Schoeberl, M. R.; Ziemke, J. R.; Bojkov, B.; Livesey, N.; Duncan, B.; Strahan, S.; Froidevaux, L.; Kulawik, S.; Bhartia, P. K.; Chandra, S.; Levelt, P. F.; Witte, J. C.; Thompson, A. M.; Cuevas, E.; Redondas, A.; Tarasick, D. W.; Davies, J.; Bodeker, G.; Hansen, G.; Johnson, B. J.; Oltmans, S. J.; Vömel, H.; Allaart, M.; Kelder, H.; Newchurch, M.; Godin Beekmann, S.; Ancellet, G.; Claude, H.; Andersen, S. B.; Kyrö, Esko; Parrondo, María Concepción; Yela González, Margarita; Zablocki, G.; Moore, D.; Dier, H.; Von der Gathen, P.; Viatte, P.; Stübi, R.; Calpini, B.; Skrivankova, P.; Dorokhov, V.; De Backer, H.; Schmidlin, F. J.; Coetzee, G.; Fujiwara, M.; Thouret, V.; Posny, F.; Morris, G.; Merrill, J.; Leong, C. P.; Koenig Langlo, G.; Joseph, E.[1] We estimate the tropospheric column ozone using a forward trajectory model to increase the horizontal resolution of the Aura Microwave Limb Sounder (MLS) derived stratospheric column ozone. Subtracting the MLS stratospheric column from Ozone Monitoring Instrument total column measurements gives the trajectory enhanced tropospheric ozone residual (TTOR). Because of different tropopause definitions, we validate the basic residual technique by computing the 200-hPa-to-surface column and comparing it to the same product from ozonesondes and Tropospheric Emission Spectrometer measurements. Comparisons show good agreement in the tropics and reasonable agreement at middle latitudes, but there is a persistent low bias in the TTOR that may be due to a slight high bias in MLS stratospheric column. With the improved stratospheric column resolution, we note a strong correlation of extratropical tropospheric ozone column anomalies with probable troposphere-stratosphere exchange events or folds. The folds can be identified by their colocation with strong horizontal tropopause gradients. TTOR anomalies due to folds may be mistaken for pollution events since folds often occur in the Atlantic and Pacific pollution corridors. We also compare the 200-hPa-to-surface column with Global Modeling Initiative chemical model estimates of the same quantity. While the tropical comparisons are good, we note that chemical model variations in 200-hPa-to-surface column at middle latitudes are much smaller than seen in the TTOR.Publicación Acceso Abierto Chemical ozone loss in the Arctic winter 2002/2003 determined with Match(EGU European Geosciences Union, 2006-07-10) Streibel, M.; Rex, M.; Von der Gathen, P.; Lehmann, R.; Harris, N. R. P.; Braathen, G. O.; Reimer, E.; Deckelmann, H.; Chipperfield, M.; Millard, G.; Allaart, M.; Andersen, S. B.; Claude, H.; Davies, J.; De Backer, H.; Dier, H.; Dorokov, V.; Fast, H.; Gerding, M.; Kyrö, Esko; Litynska, Z.; Moore, D.; Moran, E.; Nagai, T.; Nakane, H.; Parrondo, María Concepción; Skrivankova, P.; Stübi, R.; Vaughan, G.; Viatte, P.; Yushkov, V.The Match technique was used to determine chemically induced ozone loss inside the stratospheric vortex during the Arctic winter 2002/2003. From end of November 2002, which is the earliest start of a Match campaign ever, until end of March 2003 approximately 800 ozonesondes were launched from 34 stations in the Arctic and mid latitudes. Ozone loss rates were quantified from the beginning of December until mid-March in the vertical region of 400–550 K potential temperature. In accordance with the occurrence of a large area of conditions favourable for the formation of polar stratospheric clouds in December ozone destruction rates varied between 10–15 ppbv/day depending on height. Maximum loss rates around 35 ppbv/day were reached during late January. Afterwards ozone loss rates decreased until mid-March when the final warming of the vortex began. In the period from 2 December 2002 to 16 March 2003 the accumulated ozone loss reduced the partial ozone column of 400–500 K potential temperature by 56±4 DU. This value is in good agreement with that inferred from the empirical relation of ozone loss against the volume of potential polar stratospheric clouds within the northern hemisphere. The sensitivity of the results on recent improvements of the approach has been tested.
