Persona: Zorzano, María-Paz
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Instituto Nacional de Técnica Aeroespacial
El Instituto Nacional de Técnica Aeroespacial es el Organismo Público de Investigación (OPI) dependiente del Ministerio de Defensa. Además de realizar actividades de investigación científica y de desarrollo de sistemas y prototipos en su ámbito de conocimiento, presta servicios tecnológicos a empresas, universidades e instituciones.
El INTA está especializado en la investigación y el desarrollo tecnológico, de carácter dual, en los ámbitos de la Aeronáutica, Espacio, Hidrodinámica, Seguridad y Defensa.
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Publicación Acceso Abierto Space Environmental Chamber for Planetary Studies(Multidisciplinary Digital Publishing Institute, 2020-07-18) Ramachandran, Abhilash Vakkada; Nazarious, Miracle Israel; Mathanlal, Thasshwin; Zorzano, María-Paz; Martín Torres, Javier; 0000-0003-0499-6370; 0000-0002-7148-8803; 0000-0002-4492-9650; 0000-0001-6479-2236; Unidad de Excelencia Científica María de Maeztu Centro de Astrobiología del Instituto Nacional de Técnica Aeroespacial y CSIC, MDM-2017-0737We describe a versatile simulation chamber that operates under representative space conditions (pressures from < 10-5 mbar to ambient and temperatures from 163 to 423 K), the SpaceQ chamber. This chamber allows to test instrumentation, procedures, and materials and evaluate their performance when exposed to outgassing, thermal vacuum, low temperatures, baking, dry heat microbial reduction (DHMR) sterilization protocols, and water. The SpaceQ is a cubical stainless-steel chamber of 27,000 cm3 with a door of aluminum. The chamber has a table which can be cooled using liquid nitrogen. The chamber walls can be heated (for outgassing, thermal vacuum, or dry heat applications) using an outer jacket. The chamber walls include two viewports and 12 utility ports (KF, CF, and Swagelok connectors). It has sensors for temperature, relative humidity, and pressure, a UV-VIS-NIR spectrometer, a UV irradiation lamp that operates within the chamber as well as a stainless-steel syringe for water vapor injection, and USB, DB-25 ports to read the data from the instruments while being tested inside. This facility has been specifically designed for investigating the effect of water on the Martian surface. The core novelties of this chamber are: (1) its ability to simulate the Martian near-surface water cycle by injecting water multiple times into the chamber through a syringe which allows to control and monitor precisely the initial relative humidity inside with a sensor that can operate from vacuum to Martian pressures and (2) the availability of a high-intensity UV lamp, operating from vacuum to Martian pressures, within the chamber, which can be used to test material curation, the role of the production of atmospheric radicals, and the degradation of certain products like polymers and organics. For illustration, here we present some applications of the SpaceQ chamber at simulated Martian conditions with and without atmospheric water to (i) calibrate the ground temperature sensor of the Engineering Qualification Model of HABIT (HabitAbility: Brines, Irradiation and Temperature) instrument, which is a part of ExoMars 2022 mission. These tests demonstrate that the overall accuracy of the temperature retrieval at a temperature between -50 and 10 °C is within 1.3 °C and (ii) investigate the curation of composite materials of Martian soil simulant and binders, with added water, under Martian surface conditions under dry and humid conditions. Our studies have demonstrated that the regolith, when mixed with super absorbent polymer (SAP), water, and binders exposed to Martian conditions, can form a solid block and retain more than 80% of the added water, which may be of interest to screen radiation while maintaining a low weight.Publicación Acceso Abierto Atmospheric composition of exoplanets based on the thermal escape of gases and implications for habitability: Atmospheric composition of exoplanets(The Royal Society Publishing (United Kingdom), 2020-09-09) Konatham, Samuel; Martín Torres, Javier; Zorzano, María-Paz; Knut and Alice Wallenberg Foundation; 0000-0002-8831-6047; 0000-0001-6479-2236; 0000-0002-4492-9650; Unidad de Excelencia Científica María de Maeztu Centro de Astrobiología del Instituto Nacional de Técnica Aeroespacial y CSIC, MDM-2017-0737The detection of habitable exoplanets is an exciting scientific and technical challenge. Owing to the current and most likely long-lasting impossibility of performing in situ exploration of exoplanets, their study and hypotheses regarding their capability to host life will be based on the restricted low-resolution spatial and spectral information of their atmospheres. On the other hand, with the advent of the upcoming exoplanet survey missions and technological improvements, there is a need for preliminary discrimination that can prioritize potential candidates within the fast-growing list of exoplanets. Here we estimate, for the first time and using the kinetic theory of gases, a list of the possible atmospheric species that can be retained in the atmospheres of the known exoplanets. We conclude that, based on our current knowledge of the detected exoplanets, 45 of them are good candidates for habitability studies. These exoplanets could have Earth-like atmospheres and should be able to maintain stable liquid water. Our results suggest that the current definition of a habitable zone around a star should be revisited and that the capacity of the planet to host an Earth-like atmosphere to support the stability of liquid water should be added.Publicación Acceso Abierto Defects on a pyrite(100) surface produce chemical evolution of glycine under inert conditions: experimental and theoretical approaches(Royal Society of Chemistry, 2019-10-10) Gálvez Martínez, Santos; Escamilla Roa, E.; Zorzano, María-Paz; Mateo Marti, Eva; Martín Torres, J. [0000-0001-6479-2236]; Zorzano, M. P. [0000-0002-4492-9650]; Mateo Martí, E. [0000-0003-4709-4676]; Unidad de Excelencia Científica María de Maeztu Centro de Astrobiología del Instituto Nacional de Técnica Aeroespacial y CSIC, MDM-2017-0737The presence of non-stoichiometric sites on the pyrite(100) surface makes it a suitable substrate for driving the chemical evolution of the amino acid glycine over time, even under inert conditions. Spectroscopic molecular fingerprints prove a transition process from a zwitterionic species to an anionic species over time on the monosulfide enriched surface. By combining experimental and theoretical approaches, we propose a surface mechanism where the interaction between the amino acid species and the surface will be driven by the quenching of the surface states at Fe sites and favoured by sulfur vacancies. This study demonstrates the potential capability of pyrite to act as a surface catalyst.Publicación Restringido Ar+ ion bombardment dictates glycine adsorption on pyrite (1 0 0) surface: X-ray photoemission spectroscopy and DFT approach(Elsevier BV, 2020-11-15) Gálvez Martínez, Santos; Escamilla Roa, E.; Zorzano, María-Paz; Mateo Marti, Eva; Agencia Estatal de Investigación (AEI); Zorzano, M. P. [0000-0002-4492-9650]; Unidad de Excelencia Científica María de Maeztu del Centro de Astrobiología del Instituto Nacional de Técnica Aeroespacial y CSIC, MDM-2017-0737Ar+ ion sputtering on pyrite surfaces leads to the generation of sulfur vacancies and metallic iron. Our research shows that sputtering and annealing processes drive electrostatic changes on the pyrite surface, which play an important role in the molecular adsorption of glycine. While both chemical species (anion and zwitterion) adsorb on a sputtered pyrite surface, the anionic form of glycine is favoured. Nevertheless, in both treatments (sputtered or annealed surfaces), molecules evolve from zwitterionic to anionic species over time. Quantum mechanical calculations based in Density Functional Theory (DFT) suggest the energy required to generate vacancies increases with the number of vacancies produced, and the atomic charge of the Fe atoms that is next to a vacancy increases linearly with the number of vacancies. This leads to enhanced redox processes on the sputtered pyrite surface that favour the adsorption of glycine, which is confirmed experimentally by X-ray Photoemission Spectroscopy (XPS). We have investigated theoretically the efficiency of the adsorption process of the zwitterionic glycine onto vacancies sites: this reaction is exothermic, i.e. is energetically favoured and its energy increases with the number of defects, confirming the increased reactivity observed experimentally. The experiments show a treatment-dependent molecular selectivity of the pyrite surface.Publicación Acceso Abierto The HABIT (HabitAbility: Brine Irradiation and Temperature) environmental instrument for the ExoMars 2022 Surface Platform(Elsevier, 2021-03-17) Martín Torres, Javier; Zorzano, María-Paz; Soria Salinas, Álvaro; Israel Nazarious, Miracle; Konatham, Samuel; Mathanlal, Thasshwin; Vakkada Ramachandran, A.; Ramírez Luque, Juan Antonio; Mantas Nakhai, R.; 0000-0001-6479-2236; Unidad de Excelencia Científica María de Maeztu Centro de Astrobiología del Instituto Nacional de Técnica Aeroespacial y CSIC, MDM-2017-0737The HABIT (HabitAbility: Brine Irradiation and Temperature) instrument is a European payload of the ExoMars 2022 Surface Platform Kazachok that will characterize the present-day habitability at its landing place in Oxia Planum, Mars. HABIT consists of two modules: (i) EnvPack (Environmental Package) that monitors the thermal environment (air and ground), the incident ultraviolet radiation, the near-surface winds and the atmospheric dust cycle; and (ii) BOTTLE (Brine Observation Transition To Liquid Experiment), an In-situ Resource Utilization instrument to produce liquid water for future Mars exploration. BOTTLE will be used also to investigate the electrical conductivity properties of the martian atmosphere, the present-day atmospheric-ground water cycle and to evaluate if liquid water can exist on Mars in the form of brines, and for how long. These variables measured by HABIT are critical to determine the present and future habitability of the martian surface. In this paper, we describe in detail the HABIT instrument and sensors, together with the calibration of its Flight Model (FM) and the Engineering Qualification Model (EQM) versions. The EnvPack module has heritage from previous missions operating on the surface of Mars, and the environmental observations of its sensors will be directly comparable to those delivered by those missions. HABIT can provide information of the local temperature with ±0.2 °C accuracy, local winds with ±0.3 m/s, surface brightness temperature with ±0.8 °C, incident UV irradiance with 10% error of its absolute value in the UV-A, UV-B, UV-C ranges, as well as in the total UV-ABC range, and two additional wavebands, dedicated to ozone absorption. The UV observations can be used to derive the total opacity column and thus monitor the dust and ozone cycles. BOTTLE can demonstrate the hydration state of a set of four deliquescent salts, which have been found on Mars (calcium chloride, ferric sulphate, magnesium perchlorate and sodium perchlorate) by monitoring their electric conductivity (EC). The EC of the air and the dry salts under Earth ambient, clean room conditions is of the order of 0.1 μScm. We have simulated HABIT operations, within an environmental chamber, under martian conditions similar to those expected at Oxia Planum. For dry, CO atmospheric conditions at martian pressures, the air EC can be as low as 10 μScm, however it increases with the relative humidity (RH) percentage. The laboratory experiments show that after an increase from 0 to 60% RH within a few hours, the EC of the air increased up to 10 μScm, magnesium perchlorate hydrated and reached values of 10 μScm1, whereas calcium chloride deliquesced forming a liquid state with EC of 10 μScm. HABIT will operate with a regular cadence, through day and night. The Electronic Unit (EU) is protected with a heater that is activated when its temperature is below −33 °C and disabled if the temperature of the surface platform rises above −30 °C. Additionally, the heaters of the BOTTLE unit can be activated to dehydrate the salts and reset the experiment. HABIT weighs only 918 g. Its power consumption depends on the operation mode and internal temperature, and it varies between 0.7 W, for nominal operation, and 13.1 W (when heaters are turned on at full intensity). HABIT has a baseline data rate of 1.5 MB/sol. In addition to providing critical environmental observations, this light and robust instrument, will be the first demonstrator of a water capturing system on the surface of Mars, and the first European In-Situ Resource Utilization in the surface of another planet.Publicación Acceso Abierto Seasonal Variations in Atmospheric Composition as Measured in Gale Crater, Mars(American Geophysical Union: Advancing Earth and Space Science, 2019-11-12) Trainer, M. G.; Wong, Michael H.; McConnochie, Timothy; Franz, H. B.; Atreya, S. K.; Conrad, Pamela G.; Lefèvre, F.; Mahaffy, Paul R.; Malespin, C. A.; Manning, H. L. K.; Martín Torres, Javier; Martínez, Germán M.; McKay, Christopher P.; Navarro González, R.; Vicente Retortillo, Álvaro; Webster, Christopher R.; Zorzano, María-Paz; Universidad Nacional Autónoma de México (UNAM); Zorzano, M. P. [0000-0002-4492-9650]; Navarro González, R. [0000-0002-6078-7621]; Martín Torres, J. [0000-0001-6479-2236]; Vicente Retortillo, A. [0000-0002-4553-7624]; Unidad de Excelencia Científica María de Maeztu Centro de Astrobiología del Instituto Nacional de Técnica Aeroespacial y CSIC, MDM-2017-0737The Sample Analysis at Mars (SAM) instrument onboard the Mars Science Laboratory Curiosity rover measures the chemical composition of major atmospheric species (CO2, N2, 40Ar, O2, and CO) through a dedicated atmospheric inlet. We report here measurements of volume mixing ratios in Gale Crater using the SAM quadrupole mass spectrometer, obtained over a period of nearly 5 years (3 Mars years) from landing. The observation period spans the northern summer of MY 31 and solar longitude (LS) of 175° through spring of MY 34, LS = 12°. This work expands upon prior reports of the mixing ratios measured by SAM QMS in the first 105 sols of the mission. The SAM QMS atmospheric measurements were taken periodically, with a cumulative coverage of four or five experiments per season on Mars. Major observations include the seasonal cycle of CO2, N2, and Ar, which lags approximately 20–40° of LS behind the pressure cycle driven by CO2 condensation and sublimation from the winter poles. This seasonal cycle indicates that transport occurs on faster timescales than mixing. The mixing ratio of O2 shows significant seasonal and interannual variability, suggesting an unknown atmospheric or surface process at work. The O2 measurements are compared to several parameters, including dust optical depth and trace CH4 measurements by Curiosity. We derive annual mean volume mixing ratios for the atmosphere in Gale Crater: CO2 = 0.951 (±0.003), N2 = 0.0259 (±0.0006), 40Ar = 0.0194 (±0.0004), O2 = 1.61 (±0.09) x 10‐3, and CO = 5.8 (±0.8) x 10‐4.Publicación Acceso Abierto Characterizing Dust-Radiation Feedback and Refining the Horizontal Resolution of the MarsWRF Model Down to 0.5 Degree(American Geophysical Union: Advancing Earth and Space Science, 2021-02-19) Gebhardt, C.; Abuelgasim, A.; Fonseca, R. M.; Martín Torres, Javier; Zorzano, María-Paz; United Arab Emirates University (UAE University); Agencia Estatal de Investigación (AEI); Gebhardt, C. [0000-0003-4811-6267]; Abuelgasim, A. [0000-0001-8897-4181]; Fonseca, R. [0000-0002-8562-7368]; Zorzano, M. P. [0000-0002-4492-9650]; Unidad de Excelencia Científica María de Maeztu Centro de Astrobiología del Instituto Nacional de Técnica Aeroespacial y CSIC, MDM-2017-0737In this study, three simulations by the Mars Weather Research and Forecasting Model are compared: two 10 Martian year (MY) 2° × 2° simulations with (i) fully radiatively active dust and (ii) a prescribed dust scenario, and a (iii) 1 MY 0.5° × 0.5° simulation with prescribed dust as in (ii). From comparing (i) and (ii), we found that the impact of dust-radiation feedback is individually different for any region. The most striking evidence are major dust lifting activities to the south of Chryse Planitia (S-CP) seen in (i) but not in (ii). By contrast, dust lifting and deposition on the southern slopes and inside the Hellas Basin are similar in both simulations. The latter, in turn, points toward a similar near-surface atmospheric circulation. In (iii), the total global amount of wind stress lifted dust is by a factor of ∼8 higher than in (ii), with S-CP being a major lifting region as in (i). Nonetheless, the surface dust lifting by wind stress in (iii) may be also reduced regionally, as seen at the peak of Elysium Mons because of its unique topography. The zonal mean circulation in (i) is generally of a comparable strength to that in (ii), with exceptions in global dust storm years, when it is clearly stronger in (i), in line with a dustier atmosphere. The differences in the zonal mean circulation between (ii) and (iii) are mostly at lower altitudes and may arise because of differences in the representation of the topography.Publicación Acceso Abierto Subsurface robotic exploration for geomorphology, astrobiology and mining during MINAR6 campaign, Boulby Mine, UK: part I (Rover development).(Cambridge University Press, 2020-04-05) Mathanlal, Thasshwin; Bhardwaj, Anshuman; Vakkada Ramachandran, A.; Zorzano, María-Paz; Martín Torres, Javier; Cockell, Charles S.; Edwards, T.; Martín Torres, J. [0000-0001-6479-2236]; Zorzano, M. P. [0000-0002-4492-9650]; Bhardwaj, A. [0000-0002-2502-6384]; Vakkada Ramachandran, A. [0000-0003-0499-6370]; Unidad de Excelencia Científica María de Maeztu Centro de Astrobiología del Instituto Nacional de Técnica Aeroespacial y CSIC, MDM-2017-0737Autonomous exploration requires the use of movable platforms that carry a payload of instruments with a certain level of autonomy and communication with the operators. This is particularly challenging in subsurface environments, which may be more dangerous for human access and where communication with the surface is limited. Subsurface robotic exploration, which has been to date very limited, is interesting not only for science but also for cost-effective industrial exploitation of resources and safety assessments in mines. Furthermore, it has a direct application to exploration of extra-terrestrial subsurface environments of astrobiological and geological significance such as caves, lava tubes, impact or volcanic craters and subglacial conduits, for deriving in-situ mineralogical resources and establishing preliminary settlements. However, the technological solutions are generally tailor-made and are therefore considered as costly, fragile and environment-specific, further hindering their extensive and effective applications. To demonstrate the advantages of rover exploration for a broad-community, we have developed KORE (KOmpact Rover for Exploration); a low-cost, re-usable, rover multi-purpose platform. The rover platform has been developed as a technological demonstration for extra-terrestrial subsurface exploration and terrestrial mining operations pertaining to geomorphological mapping, environmental monitoring, gas leak detections and search and rescue operations in case of an accident. The present paper, the first part of a series of two, focuses on describing the development of a robust rover platform to perform dedicated geomorphological, astrobiological and mining tasks. KORE was further tested in the Mine Analogue Research 6 (MINAR6) campaign during September 2018 in the Boulby mine (UK), the second deepest potash mine in Europe at a subsurface depth of 1.1 km, the results of which will be presented in the second paper of this series. KORE is a large, semi-autonomous rover weighing 160 kg with L x W x H dimensions 1.2 m x 0.8 m x 1 m and a payload carrying capacity of 100 kg using 800 W traction power that can power to a maximum speed of 8.4 km h(-1). The rover can be easily dismantled in three parts facilitating its transportation to any chosen site of exploration. Presently, the main scientific payloads on KORE are: (1) a three-dimensional mapping camera, (2) a methane detection system, (3) an environmental station capable of monitoring temperature, relative humidity, pressure and gases such as NO2, SO2, H2S, formaldehyde, CO, CO2, O-3, O(2,)volatile organic compounds and particulates and (4) a robotic arm. Moreover, the design of the rover allows for integration of more sensors as per the scientific requirements in future expeditions. At the MINAR6 campaign, the technical readiness of KORE was demonstrated during 6 days of scientific research in the mine, with a total of 22 h of operation.Publicación Acceso Abierto Small lava caves as possible exploratory targets on Mars: Analogies drawn from UAV imaging of an Icelandic lava field(Multidisciplinary Digital Publishing Institute, 2020-06-19) Sam, Lydia; Bhardwaj, Anshuman; Singh, Shaktiman; Martín Torres, Javier; Zorzano, María-Paz; Ramírez Luque, Juan Antonio; 0000-0003-3181-2960; 0000-0002-2502-6384; 0000-0003-4304-388; 0000-0002-4492-9650; Unidad de Excelencia Científica María de Maeztu Centro de Astrobiología del Instituto Nacional de Técnica Aeroespacial y CSIC, MDM-2017-0737Volcanic-aeolian interactions and processes have played a vital role in landscape evolution on Mars. Martian lava fields and associated caves have extensive geomorphological, astrobiological, and in-situ resource utilization (ISRU) implications for future Mars missions which might be focused on subsurface exploration. Although several possible cave “skylights” of tens to >100 m diameter have been spotted in lava fields of Mars, there is a possibility of prevalence of meter-scale features which are an order of magnitude smaller and difficult to identify but could have vital significance from the scientific and future exploration perspectives. The Icelandic volcanic-aeolian environment and fissure volcanoes can serve as analogs to study lava flow-related small caves such as surface tubes, inflationary caves, liftup caves, and conduits. In the present work, we have tried to explore the usability of unmanned aerial vehicle (UAV)-derived images for characterizing a solidified lava flow and designing a sequential methodology to identify small caves in the lava flow. In the mapped area of ~0.33 km2, we were able to identify 81 small cave openings, five lava flow morphologies, and five small cave types using 2 cm/pixel high-resolution images. The results display the usefulness of UAV imaging for such analogous research, and also highlight the possibility of the widespread presence of similar small cave openings in Martian lava fields. Such small openings can facilitate optimal air circulation within the caves while sheltering the insides from physical weathering and harmful radiations. Using the available best resolution remote sensing images, we extend the analogy through the contextual and geomorphological analysis of several possible pit craters in the Tharsis region of Mars, in a region of extremely vesicular and fragile lava crust with pahoehoe-type morphology. We report two possible pit craters in this region, with diameters as small as ~20 m. The possibility that such small cave openings can lead to vast subterranean hollow spaces on Mars cannot be ruled out considering its low gravity.Publicación Restringido Cirrus-induced shortwave radiative effects depending on their optical and physical properties: Case studies using simulations and measurements(Elsevier BV, 2020-12-01) Córdoba Jabonero, C.; Gómez Martín, L.; Del Águila, A.; Vilaplana, Jose Manuel; López Cayuela, M. A.; Zorzano, María-Paz; Agencia Estatal de Investigación (AEI); European Research Council (ERC); Ministerio de Economía y Competitividad (MINECO); 000-0002-6655-7659; 0000-0002-4492-9650; 0000-0002-8825-830X; 0000-0003-4859-471X; Unidad de Excelencia Científica María de Maeztu Centro de Astrobiología del Instituto Nacional de Técnica Aeroespacial y CSIC, MDM-2017-0737Cirrus (Ci) clouds play an important role in the atmospheric radiative balance, and hence in Climate Change. In this work, a polarized Micro-Pulse Lidar (P-MPL), standard NASA/Micro Pulse NETwork (MPLNET) system, deployed at the INTA/El Arenosillo station in Huelva (SW Iberian Peninsula) is used for Ci detection and characterization for the first time at this site. Three days were selected on the basis of the predominantly detected Ci clouds in dependence on their cloud optical depth (COD). Hence, three Ci cloud categories were examined at day-times for comparison with solar radiation issues: 19 cases of sub-visuals (svCi, COD: 0.01-0.03) on 1 October 2016, 7 cases of semitransparents (stCi, COD: 0.03-0.30) on 8 May 2017, and 17 cases of opaques (opCi, COD: 0.3-3.0) on 28 October 2016. Their radiative-relevant optical, macro- and micro-physical properties were retrieved. The mean COD for the svCi, stCi and opCi groups was 0.02 +/- 0.01, 0.22 +/- 0.08 and 0.93 +/- 0.40, respectively; in overall, their lidar ratio ranged between 25 and 35 sr. Ci clouds were detected at 11-13 km height (top boundaries) with geometrical thicknesses of 1.7-2.0 km. Temperatures reported at those altitudes corresponded to lower values than the thermal threshold for homogenous ice formation. Volume linear depolarization ratios of 0.3-0.4 (and normalized backscattering ratios higher than 0.9) also confirmed Ci clouds purely composed of ice particles. Their effective radius was within the interval of 9-15 mu m size, and the ice water path ranged from 0.02 (svCi) to 9.9 (opCi) g m(-2). The Cirrus Cloud Radiative Effect (CCRE) was estimated using a Radiative Transfer (RT) model for Ci-free conditions and Ci-mode (Ci presence) scenarios. RT simulations were performed for deriving the CCRE at the top-of-atmosphere (TOA) and on surface (SRF), and also the atmospheric CCRE, for the overall shortwave (SW) range and their spectral sub-intervals (UV, VIS and NIR). A good agreement was first obtained for the RT simulations as validated against solar radiation measurements under clean conditions for solar zenith angles less than 75 degrees (differences were mainly within +/- 20 W m(-2) and correlation coefficients close to 1). By considering all the Ci clouds, independently on their COD, the mean SW CCRE values at TOA and SRF were, respectively, -30 +/- 26 and -24 +/- 19 W m(-2), being the mean atmospheric CCRE of -7 +/- 7 W m(-2); these values are in good agreement with global annual estimates found for Ci clouds. By using linear regression analysis, a Ci-induced enhancing cooling radiative effect was observed as COD increased for all the spectral ranges, with high correlations. In particular, the SW CCRE at TOA and SRF, and the atmospheric CCRE, presented COD-dependent rates of -74 +/- 4, -55 +/- 5, -19 +/- 2 W m(-2) tau(-1), respectively. Additionally, increasing negative rates are found from UV to NIR for each Ci category, reflecting a higher cooling NIR contribution w.r.t. UV and VIS ranges to the SW CCRE, and being also more pronounced at the TOA w.r.t. on SRF, as expected. The contribution of the SW CCRE to the net (SW + LW) radiative balance can be also potentially relevant. These results are especially significant for space-borne photometric/radiometric instrumentation and can contribute to validation purposes of the next ESA's EarthCARE mission, whose principal scientific goal is focused on radiation-aerosol-cloud interaction research.
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