Persona: Jimenez-Serra, Izaskun
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Centro de Astrobiologia
El Centro de Astrobiología (CAB) es un centro mixto de investigación en astrobiología, dependiente tanto del Instituto Nacional de Técnica Aeroespacial (INTA) como del Consejo Superior de Investigaciones Científicas (CSIC).
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Jimenez-Serra
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Izaskun
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Publicación Acceso Abierto The Origin of the E/Z Isomer Ratio of Imines in the Interstellar Medium(IOP Science Publishing, 2021-04-29) García de la Concepción, J.; Jimenez-Serra, Izaskun; Corchado, J. C.; Rivilla, Victor M.; Martín Pintado, J.; Agencia Estatal de Investigación (AEI); Comunidad de Madrid; Junta de Andalucía; García de la Concepción, j. [0000-0001-6484-9546]; Jiménez Serra, I. [0000-0003-4493-8714]; Corchado, J. C. [0000-0002-8463-3168]; Rivilla, V. M. [0000-0002-2887-5859]; Martín Pintado, J. [0000-0003-4561-3508]; Unidad de Excelencia Científica María de Maeztu Centro de Astrobiología del Instituto Nacional de Técnica Aeroespacial y CSIC, MDM-2017-0737Recent astronomical observations of both isomers E and Z of imines such as cyanomethanimine, ethanimine, and 2-propyn-1-imine have revealed that the abundances in the interstellar medium (ISM) of these isomers differ by factors of ~3–10. Several theories have been proposed to explain the observed behavior, but none of them successfully explains the [E]/[Z] ratios. In this work we present a detailed study of the kinetics of the one-step E-Z isomerization reactions of cyanomethanimine, ethanimine, and 2-propyn-1-imine under interstellar conditions (in the 10–400 K temperature range). This reaction was previously thought to be nonviable in the ISM due to its associated high-energy barrier (about 13,000 K). In this Letter, we show that considering the multidimensional small curvature tunneling approximation, the tunneling effect enables the isomerization even at low temperatures. This is due to the fact that the representative tunneling energy lies in the vibrational ground state of the least stable isomer up to approximately 150 K, making the reaction constants of the isomerization from the least stable to the most stable isomer basically constant. The predicted [E]/[Z] ratios are almost the same as those reported from the astronomical observations for all imines observed. This study demonstrates that the [E]/[Z] ratio of imines in the ISM strongly depends on their relative stability.Publicación Acceso Abierto Thiols in the Interstellar Medium: First Detection of HC(O)SH and Confirmation of C2H5SH(IOP Science Publishing, 2021-04-30) Rodríguez Almeida, L. F.; Jimenez-Serra, Izaskun; Rivilla, Victor M.; Martín Pintado, J.; Zeng, S.; Tercero, B.; De Vicente, P.; Colzi, L.; Rico Villas, F.; Martín, S.; Requena Torres, Miguel Angel; Comunidad de Madrid; Agencia Estatal de Investigación (AEI); European Research Council (ERC); European Commission (EC); Rodríguez Almeida, L. F. [0000-0002-9785-703X]; Jiménez Serra, I. [0000-0003-4493-8714]; Rivilla, V. M. [0000-0002-2887-5859]; Martín Pintado, J. [0000-0003-4561-3508]; Tercero, B. [0000-0002-4782-5259]; Martín, S. [0000-0001-9281-2919]; Unidad de Excelencia Científica María de Maeztu Centro de Astrobiología del Instituto Nacional de Técnica Aeroespacial y CSIC, MDM-2017-0737The chemical compounds carrying the thiol group (-SH) have been considered essential in recent prebiotic studies regarding the polymerization of amino acids. We have searched for this kind of compound toward the Galactic Center quiescent cloud G+0.693–0.027. We report the first detection in the interstellar space of the trans-isomer of monothioformic acid (t-HC(O)SH) with an abundance of ~1 × 10−10. Additionally, we provide a solid confirmation of the gauche isomer of ethyl mercaptan (g-C2H5SH) with an abundance of ~3 × 10−10, and we also detect methyl mercaptan (CH3SH) with an abundance of ~5 × 10−9. Abundance ratios were calculated for the three SH-bearing species and their OH analogs, revealing similar trends between alcohols and thiols with increasing complexity. Possible chemical routes for the interstellar synthesis of t-HC(O)SH, CH3SH, and C2H5SH are discussed, as well as the relevance of these compounds in the synthesis of prebiotic proteins in the primitive Earth.Publicación Acceso Abierto FAUST. II. Discovery of a Secondary Outflow in IRAS 15398−3359: Variability in Outflow Direction during the Earliest Stage of Star Formation?(The Institute of Physics (IOP), 2021-03-22) Okoda, Y.; Oya, Y.; Francis, L.; Johnstone, D.; Inutsuka, S. I.; Ceccarelli, C.; Codella, C.; Chandler, C. J.; Sakai, N.; Aikawa, Y.; Alves, F.; Balucani, N.; Bianchi, E.; Bouvier, M.; Caselli, P.; Caux, E.; Charnley, S.; Choudhury, S.; De Simone, M.; Dulieu, F.; Durán, A.; Evans, L.; Favre, C.; Fedele, D.; Feng, S.; Fontani, F.; Hama, T.; Hanawa, T.; Herbst, E.; Hirota, T.; Imai, M.; Isella, A.; Jimenez-Serra, Izaskun; Kahane, C.; Lefloch, B.; Loinard, L.; López Sepulcre, A.; Maud, L. T.; Maureira, M. J.; Ménard, F.; Mercimek, S.; Miotello, A.; Moellenbrock, G.; Mori, S.; Murillo, Nadia M.; Nakatani, R.; Nomura, H.; Oba, Y.; O´Donoghue, R.; Ohashi, S.; Ospina Zamudio, J.; Pineda, Jaime E.; Podio, L.; Rimola, A.; Sakai, T.; Segura Cox, D.; Shirley, Y.; Svoboda, B.; Taquet, V.; Testi, L.; Vastel, C.; Viti, S.; Watanabe, N.; Watanabe, Y.; Witzel, A.; Xue, C.; Zhang, Y.; Zhao, B.; Yamamoto, S.; European Research Council (ERC); Agencia Estatal de Investigación (AEI); Japan Society for the Promotion of Science (JSPS); Okoda, Y. [0000-0003-3655-5270]; Oya, Y. [0000-0002-0197-8751]; Francis, L. [0000-0001-8822-6327]; Johnstone, D. [0000-0002-6773-459X]; Inutsuka, S. I. [0000-0003-4366-6518]; Ceccarelli, C. [0000-0001-9664-6292]; Codella, C. [0000-0003-1514-3074]; Chandler, C. [0000-0002-7570-5596]; Sakai, N. [0000-0002-3297-4497]; Aikawa, Y. [0000-0003-3283-6884]; Alves, F. [0000-0002-7945-064X]; Balucani, N. [0000-0001-5121-5683]; Bianchi, E. [0000-0001-9249-7082]; Bouvier, M. [0000-0003-0167-0746]; Caselli, P. [0000-0003-1481-7911]; De Simone, M. [0000-0001-5659-0140]; Feng, S. [0000-0002-4707-8409]; Fontani, F. [0000-0003-0348-3418]; Hama, T. [0000-0002-4991-4044]; Hanawa, T. [0000-0002-7538-581X]; Herbst, E. [0000-0002-4649-2536]; Hirota, T. [0000-0003-1659-095X]; Imai, M. [0000-0002-5342-6262]; Isella, A. [0000-0001-8061-2207]; Jiménez Serra, I. [0000-0003-4493-8714]; Kahane, C. [0000-0003-1691-4686]; Loinard, L. [0000-0002-5635-3345]; López Sepulcre, A. [0000-0002-6729-3640]; Maud, L. T. [0000-0002-7675-3565]; Maureira, M. J. [0000-0002-7026-8163]; Menard, F. [0000-0002-1637-7393]; Miotello, A. [0000-0002-7997-2528]; Moellenbrock, G. [0000-0002-3296-8134]; Oba, Y. [0000-0002-6852-3604]; Ohashi, S. [0000-0002-9661-7958]; Pineda, J. E. [0000-0002-3972-1978]; Rimola, A. [0000-0002-9637-4554]; Sakai, T. [0000-0003-4521-7492]; Segura Cox, D. [0000-0003-3172-6763]; Svoboda, B. [0000-0002-8502-6431]; Taquet, V. [0000-0003-0407-7489]We have observed the very low-mass Class 0 protostar IRAS 15398−3359 at scales ranging from 50 to 1800 au, as part of the Atacama Large Millimeter/Submillimeter Array Large Program FAUST. We uncover a linear feature, visible in H2CO, SO, and C18O line emission, which extends from the source in a direction almost perpendicular to the known active outflow. Molecular line emission from H2CO, SO, SiO, and CH3OH further reveals an arc-like structure connected to the outer end of the linear feature and separated from the protostar, IRAS 15398−3359, by 1200 au. The arc-like structure is blueshifted with respect to the systemic velocity. A velocity gradient of 1.2 km s−1 over 1200 au along the linear feature seen in the H2CO emission connects the protostar and the arc-like structure kinematically. SO, SiO, and CH3OH are known to trace shocks, and we interpret the arc-like structure as a relic shock region produced by an outflow previously launched by IRAS 15398−3359. The velocity gradient along the linear structure can be explained as relic outflow motion. The origins of the newly observed arc-like structure and extended linear feature are discussed in relation to turbulent motions within the protostellar core and episodic accretion events during the earliest stage of protostellar evolution.Publicación Acceso Abierto Prebiotic Precursors of the Primordial RNA World in Space: Detection of NH2OH(The Institute of Physics (IOP), 2020-08-19) Rivilla, Victor M.; Martín Pintado, J.; Jimenez-Serra, Izaskun; Martín, S.; Rodríguez Almeida, L. F.; Requena Torres, Miguel Angel; Rico Villas, F.; Zeng, S.; Briones, C.; European Research Council (ERC); Agencia Estatal de Investigación (AEI); Comunidad de Madrid; Briones, C. [0000-0003-2213-8353]; Martín Ruiz, S. [0000-0001-9281-2919]; Rico Villas, F. [0000-0002-5351-3497]; Rivilla, V. M. [0000-0002-2887-5859]; Unidad de Excelencia Científica María de Maeztu Centro de Astrobiología del Instituto Nacional de Técnica Aeroespacial y CSIC, MDM-2017-0737One of the proposed scenarios for the origin of life is the primordial RNA world, which considers that RNA molecules were likely responsible for the storage of genetic information and the catalysis of biochemical reactions in primitive cells, before the advent of proteins and DNA. In the last decade, experiments in the field of prebiotic chemistry have shown that RNA nucleotides can be synthesized from relatively simple molecular precursors, most of which have been found in space. An important exception is hydroxylamine, NH2OH, which, despite several observational attempts, it has not been detected in space yet. Here we present the first detection of NH2OH in the interstellar medium toward the quiescent molecular cloud G+0.693-0.027 located in the Galactic Center. We have targeted the three groups of transitions from the J = 2−1, 3−2, and 4−3 rotational lines, detecting five transitions that are unblended or only slightly blended. The derived molecular abundance of NH2OH is (2.1 ± 0.9) × 10−10. From the comparison of the derived abundance of NH2OH and chemically related species, with those predicted by chemical models and measured in laboratory experiments, we favor the formation of NH2OH in the interstellar medium via hydrogenation of NO on dust grain surfaces, with possibly a contribution of ice-mantle NH3 oxidation processes. Further laboratory studies and quantum chemical calculations are needed to completely rule out the formation of NH2OH in the gas phase.Publicación Acceso Abierto FAUST I. The hot corino at the heart of the prototypical Class I protostar L1551 IRS5.(Oxford Academics: Oxford University Press, 2020-07-21) Bianchi, S.; Chandler, C. J.; Ceccarelli, C.; Codella, C.; Sakai, N.; López Sepulcre, A.; Maud, L. T.; Moellenbrock, G.; Svoboda, B.; Watanabe, Y.; Sakai, T.; Ménard, F.; Aikawa, Y.; Alves, F.; Balucani, N.; Bouvier, M.; Caselli, P.; Caux, E.; Charnley, S.; Choudhury, S.; De Simone, M.; Dulieu, F.; Durán, A.; Evans, L.; Favre, C.; Fedele, D.; Feng, S.; Fontani, F.; Francis, L.; Hama, T.; Hanawa, T.; Herbst, E.; Hirota, T.; Imai, M.; Isella, A.; Jimenez-Serra, Izaskun; Johnstone, D.; Kahane, C.; Lefloch, B.; Loinard, L.; Maureira, M. J.; Mercimek, S.; Miotello, A.; Mori, S.; Nakatani, R.; Nomura, H.; Oba, Y.; Ohashi, S.; Okoda, Y.; Ospina Zamudio, J.; Oya, Y.; Pineda, Jaime E.; Podio, L.; Rimola, A.; Segura Cox, D.; Shirley, Y.; Taquet, V.; Testi, L.; Vastel, C.; Viti, S.; Watanabe, N.; Witzel, A.; Xue, C.; Zhao, B.; Zhang, Y.; Yamamoto, S.; European Research Council (ERC); Japan Society for the Promotion of Science (KAKENHI); Agencia Estatal de Investigación (AEI); Universidad Nacional Autónoma de México (UNAM); Agence Nationale de la Recherche (ANR); Balucani, N. [0000-0001-5121-5683]; De Oliveira Alves, F. [0000-0002-7945-064X]; Hama, T. [0000-0002-4991-4044]; Ohashi, S. [0000-0002-9661-7958]; Johnstone, D. [0000-0002-6773-459X]; Watanabe, Y. [0000-0002-9668-3592]; Ceccarelli, C. [0000-0001-9664-6292]; Pineda, J. [0000-0002-3972-1978]; Fedele, D. [0000-0001-6156-0034]; Mercimek, S. [0000-0002-0742-7934]; Xue, C. [0000-0003-2760-2119]; Sakai, N. [0000-0002-3297-4497]; Unidad de Excelencia Científica María de Maeztu Centro de Astrobiología del Instituto Nacional de Técnica Aeroespacial y CSIC, MDM-2017-0737The study of hot corinos in solar-like protostars has been so far mostly limited to the Class 0 phase, hampering our understanding of their origin and evolution. In addition, recent evidence suggests that planet formation starts already during Class I phase, which therefore represents a crucial step in the future planetary system chemical composition. Hence, the study of hot corinos in Class I protostars has become of paramount importance. Here, we report the discovery of a hot corino towards the prototypical Class I protostar L1551 IRS5, obtained within the ALMA (Atacama Large Millimeter/submillimeter Array) Large Program FAUST (Fifty AU STudy of the chemistry in the disc/envelope system of solar-like protostars). We detected several lines from methanol and its isotopologues (13CH3OH and CH2DOH), methyl formate, and ethanol. Lines are bright towards the north component of the IRS5 binary system, and a possible second hot corino may be associated with the south component. The methanol lines' non-LTE analysis constrains the gas temperature (∼100 K), density (≥1.5 × 108 cm−3), and emitting size (∼10 au in radius). All CH3OH and 13CH3OH lines are optically thick, preventing a reliable measure of the deuteration. The methyl formate and ethanol relative abundances are compatible with those measured in Class 0 hot corinos. Thus, based on this work, little chemical evolution from Class 0 to I hot corinos occurs.Publicación Acceso Abierto Synthesis and Spectroscopic Characterization of Interstellar Candidate Ethynyl Thiocyanate: HCCSCN(IOP Publishing, 2024-11-14) Alonso, Elena R.; Insausti, Aran; Kolesniková, Lucie; León, Iker; McGuire, Brett A.; Shingledecker, Christopher N.; Agúndez, Marcelino; Cernicharo, José; Rivilla, Victor M.; Cabezas, Carlos; Jimenez-Serra, Izaskun; Martín-Pintado, Jesús; Guillemin, Jean Claude; National Science Foundation (NSF); Junta de Castilla y León; European Commission (EC); El Consejo Superior de Investigaciones Científicas (CSIC); Centre National de la Recherche Scientifique (CNRS); Ministerio de Ciencia e Innovación (MICINN)This work aims to spectroscopically characterize and provide for the first time direct experimental frequencies of the ground vibrational state and two excited states of the simplest alkynyl thiocyanate (HCCSCN) for astrophysical use. Both microwave (8-16 GHz) and millimeter-wave regions (50-120 GHz) of the spectrum have been measured and analyzed in terms of Watson’s semirigid rotor Hamiltonian. A total of 314 transitions were assigned to the ground state of HCCSCN, and a first set of spectroscopic constants have been accurately determined. Spectral features of the molecule were then searched for in Sgr B2(N), NGC 6334I, G+0.693−0.027, and TMC-1 molecular clouds. Upper limits to the column density are provided.Publicación Acceso Abierto Vibrationally excited HC3N emission in NGC 1068: tracing the recent star formation in the starburst ring(Oxford Academics: Oxford University Press, 2021-01-25) Rico Villas, F.; Martín Pintado, J.; González Alfonso, E.; Rivilla, Victor M.; Martín, S.; García Burillo, S.; Jimenez-Serra, Izaskun; Sánchez García, M.; Agencia Estatal de Investigación (AEI); European Research Council (ERC); Rivilla, V. M. [0000-0002-2887-5859]; Unidad de Excelencia Científica María de Maeztu Centro de Astrobiología del Instituto Nacional de Técnica Aeroespacial y CSIC, MDM-2017-0737Using the ALMA data, we have studied the HC3N and continuum emission in the starburst pseudo-ring (SB pseudo-ring) and the circumnuclear disc (CND) of the SB/active galactic nucleus (AGN) composite galaxy NGC 1068. We have detected emission from vibrationally excited HC3N (HC3N*) only towards one star-forming region of the SB pseudo-ring. Remarkably, HC3N* was not detected towards the CND despite its large HC3N v = 0 column density. From local thermodynamic equilibrium (LTE) and non-LTE modelling of HC3N*, we obtained a dust temperature (Tdust) of ∼250 K and a density (nH2) of 6×105 cm−3 for this star-forming region. The estimated infrared (IR) luminosity of 5.8 × 108 L⊙ is typical of proto-superstar clusters (proto-SSCs) observed in the SB galaxy NGC 253. We use the continuum emissions at 147 and 350 GHz, along with CO and Pa α, to estimate the ages of other 14 SSCs in the SB pseudo-ring. We find the SSCs to be associated with the region connecting the nuclear bar with the SB pseudo-ring, supporting the inflow scenario. For the CND, our analysis yields Tdust ≤ 100 K and nH2∼(3−6)×105 cm−3. The very different dust temperatures found for the CND and the proto-SSC indicate that, while the dust in the proto-SSC is being efficiently heated from the inside by the radiation from massive protostars, the CND is being heated externally by the AGN, which in the IR optically thin case can only heat the dust to 56 K. We discuss the implications of the non-detection of HC3N* near the luminous AGN in NGC 1068 on the interpretation of the HC3N* emission observed in the SB/AGN composite galaxies NGC 4418 and Arp 220.Publicación Acceso Abierto 2-aminooxazole in Astrophysical Environments: IR Spectra and Destruction Cross Sections for Energetic Processing(IOP Science Publishing, 2021-03-11) Maté, B.; Carrasco Herrera, R.; Timón, V.; Tanarro, I.; Herrero, V. J.; Carrascosa, H.; Muñoz Caro, G. M.; González Díaz, C.; Jimenez-Serra, Izaskun; Agencia Estatal de Investigación (AEI); 0000-0002-5478-8644; 0000-0002-1217-6834; 0000-0002-1888-513X; 0000-0002-7456-4832; 0000-0002-2885-4847; 0000-0001-7003-7368; 0000-0002-8789-9148; 0000-0003-4493-8714; Unidad de Excelencia Científica María de Maeztu Centro de Astrobiología del Instituto Nacional de Técnica Aeroespacial y CSIC, MDM-2017-07372-aminooxazole (2AO), a N-heterocyclic molecule, has been proposed as an intermediate in prebiotic syntheses. It has been demonstrated that it can be synthesized from small molecules such as cyanamide and glycoaldehyde, which are present in interstellar space. The aim of this work is to provide infrared (IR) spectra, in the solid phase for conditions typical of astrophysical environments and to estimate its stability toward UV photons and cosmic rays. IR (4000–600 cm−1) absorption spectra at 20 K, 180 K, and 300 K, IR band strengths, and room-temperature UV (120–250 nm) absorption spectra are given for the first time for this species. Destruction cross sections of ≈9.5 10−18 cm2 and ≈2 10−16 cm2 were found in the irradiation at 20 K of pure 2AO and 2AO:H2O ices with UV (6.3–10.9 eV) photons or 5 keV electrons, respectively. These data were used to estimate half-life times for the molecule in different environments. It is estimated that 2AO could survive UV radiation and cosmic rays in the ice mantles of dense clouds beyond cloud collapse. In contrast, it would be very unstable on the surface of cold solar system bodies like Kuiper Belt objects, but the molecule could still survive within dust grain agglomerates or cometesimals.Publicación Acceso Abierto Strong parameter hierarchy in the interstellar phosphorus chemical network(Frontiers in Bioscience Publications, 2025-07-30) Marina, Fernández-Ruz; Jimenez-Serra, Izaskun; Castro, Mario; Ruiz-Bermejo, Marta; Aguirre, Jacobo; European Research Council (ERC); Ministerio de Ciencia e Innovación (MICINN); Consejo Superior de Investigaciones Científicas (CSIC)Phosphorus-bearing molecules are fundamental for life on Earth, yet their astrochemical origins remain poorly understood. Their formation in the interstellar medium has been challenging to elucidate due to limited spectroscopic detections and the reliance on theoretical models that depend on numerous kinetic parameters whose values are very uncertain. Multi-parameter models often suffer from “sloppiness”, where many parameter combinations exhibit negligible influence on model outcomes, while a few dominate system behavior. In this study, we introduce the Fisher Information Spectral Reduction (FISR) algorithm, a novel and computationally efficient method to reduce the complexity of such sloppy models. Our approach exposes the strong parameter hierarchy governing these systems by identifying and eliminating parameters associated with insensitive directions in the parameter space. Applying this methodology to the phosphorus astrochemistry network, we reduce the number of reaction rate coefficients from 14 to 3, pinpointing the key reactions and kinetic parameters responsible for forming PO and PN, the main phosphorus-bearing molecules typically detected in interstellar space. The simplified model retains its predictive accuracy, offering deeper insights into the mechanisms driving phosphorus chemistry in the interstellar medium. This methodology is applicable to multi-parameter models of any kind and, specifically in astrochemistry, facilitates the development of simpler, more realistic and interpretable models to effectively guide targeted observational efforts.Publicación Restringido Detection of the elusive dangling OH ice features at ~2.7 μm in Chamaeleon I with JWST NIRCam(Nature Publishing Group, 2024-09-01) Noble, Jennifer; Fraser, Helen; Smith, Z. L.; Dartois, E.; Boogert, A. C. A.; Cuppen, Herma; Dickinson, Hugh J.; Dulieu, F.; Egami, E.; Erkal, Jessica; Giuliano, B. M.; Husquinet, Basile; Lamberts, T.; Maté, B.; McClure, Melissa; Palumbo, M. E.; Shimonishi, T.; Sun, F.; Bergner, Jennifer; Brown, Wendy; Caselli, P.; Congiu, E.; Drozdovskaya, Maria Nikolayevna; Herrero, V. J.; Ioppolo, Sergio; Jimenez-Serra, Izaskun; Linnartz, Harold; Melnick, G. J.; McGuire, Brett; Oberg, Karin; Perotti, G.; Qasim, D.; Rocha, Will Robson Monteiro; Urso, Riccardo GiovanniAscertaining the morphology and composition of the icy mantles covering dust grains in dense, cold regions of the interstellar medium is essential to developing accurate astrochemical models, determining conditions for ice formation, constraining chemical interactions in and on icy grains and understanding how ices withstand space radiation. The widely observed infrared spectroscopic signature of H2O ice at ~3 μm discriminates crystalline from amorphous structures in interstellar ices. Weaker bands seen only in laboratory ice spectra at ~2.7 μm, termed ‘dangling OH’ (dOH), are attributed to water molecules not fully bound to neighbouring water molecules and are often considered as tracing the degree of ice compaction. We exploit the high sensitivity of JWST NIRCam to detect two dOH features at 2.703 and 2.753 μm along multiple lines of sight probing the dense cloud Chamaeleon I, attributing these signatures to unbound dOH in cold water ice and dOH in interaction with other molecular species. These detections open a path to using the dOH features as tracers of the formation, composition, morphology and evolution of icy grains during the star and planet formation process.
